Heat of sorption

The sorption (desorption) of moisture in a porous material is accompanied by a variation of energy in the system. In order to better characterize this phenomenon, moisture content and temperature variations are simultaneously measured at high temporal and spatial resolution. To achieve this, various porous materials are subjected to a controlled sorption (desorption) process in a micro wind tunnel developed in-house. The moisture content variations are obtained by neutron radiography and Gravimetry. The temperature variations are measured by thermocouples inserted at various locations inside the samples.

These experimental results are analyzed in terms of energy variations and are used to validate sorption (desorption) models.

Enlarged view: Total weight variation during uptake – Experimental and modeled
Total weight variation during uptake – Experimental and modeled
Weight variations at different heights in the sample during uptake – Experimental and modeled
Enlarged view: Weight variations at different heights in the sample during uptake – Experimental and modeled
Weight variations at different heights in the sample during uptake – Experimental and modeled
Temperature variations at different heights in the sample during uptake – Experimental and modeled
Enlarged view: Temperature variations at different heights in the sample during uptake – Experimental and modeled
Temperature variations at different heights in the sample during uptake – Experimental and modeled

Publications

Desmarais G, Carl S, Radu A, Mannes D, Derome D, Carmeliet J, Spatially-resolved investigation of heat of sorption in hygroscopic porous materials, Poster at the 8th International conference on porous media, May 9-12 2016, Cincinnati, Ohio, USA

Desmarais G, Carl S, Radu A, Mannes D, Derome D, Carmeliet J, Insights on heat of sorption in porous materials using neutron radiography, Presentation at the 8th Topical day on Imaging and imaging analysis, 6 April 2016, Empa Akademie, Dübendorf.

Desmarais G, Carl  S, Kaestner A, Derome D, Carmeliet J, Sorption in porous materials – insights on heat of sorption, Presentation at the 7th International conference on porous media, May 18-21 2015, Padova, Italy

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